4-Methoxy-3-(trifluoromethyl)aniline
نویسنده
چکیده
In title compound, C(8)H(8)F(3)NO, the meth-oxy group is inclined at 8.7 (4)° to the benzene ring plane. The crystal structure is stabilized by inter-molecular N-H⋯F, N-H⋯N and C-H⋯F hydrogen-bonding inter-actions.
منابع مشابه
4-Methoxy-2-nitro-4′-(trifluoromethyl)biphenyl
The title compound, C(14)H(10)F(3)NO(3), was prepared by a palladium-catalysed Suzuki-Miyaura coupling reaction. The dihedral angle between the nitro group and its parent benzene ring is 66.85 (19)° while the dihedral angle between the two benzene rings is 49.98 (9)°. The CF(3) group is disordered over two sets of sites with occupancies of 0.457 (8) and 0.543 (8).
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The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro-meth-yl)aniline. The cyclo-penta-dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°...
متن کامل4-Methoxy-N-(2-nitrobenzylidene)aniline
The title compound, C(14)H(12)N(2)O(3), was prepared by reaction of 2-nitro-benzaldehyde with 4-methoxy-benzenamine at 377 K. The molecule has an E configuration, with a dihedral angle between the two benzene rings of 43.3 (5)°. An intermolecular C-H⋯O interaction links molecules in zigzag chains down the a axis.
متن کاملN-(4-Chlorophenyl)-4-methoxy-3-(propanamido)benzamide cyclohexane hemisolvate
The title compound, C(17)H(17)ClN(2)O(3)·0.5C(6)H(12), was prepared by the condensation reaction of 4-meth-oxy-3-(propanamido)-benzoic acid with 4-chloro-aniline. The Cl atom, the propionyl CH(3) group and the cyclo-hexyl CH(2) group are disordered over two sets of sites of equal occupancy in both mol-ecules. The cyclo-hexane solvent mol-ecule is disordered over two orientations which were mode...
متن کاملDiethyl 2-{[2-(trifluoromethyl)anilino]methylidene}propanedioate
The title compound, C(15)H(16)F(3)NO(4), is an N-substituted derivative of ortho-trifluoro-methyl-aniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from classical intra-molecular N-H⋯O and N-H⋯F hydrogen bonds, inter-molecular C-H⋯O contacts are observed, the latt...
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